A re-investigation of 4JFF and 5JFF nuclear spin–spin couplings in substituted benzenes, a novel conformational tool-Reference-Cited by-同舟云学术

A re-investigation of 4JFF and 5JFF nuclear spin–spin couplings in substituted benzenes, a novel conformational tool

Published:2016 Issue:23 Volume:18 Page:15822-15827
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Abraham Raymond J.¹²³⁴,Cooper M. Ashley¹²³⁴

Affiliation:

1. Department of Chemistry

2. The University of Liverpool

3. Liverpool L69 7ZD

4. UK

Abstract

The FF couplings in fluorobenzenes are separated into their σ and π components and this provides a novel method of determining the conformation of the C-1 substituent in 2,6-difluorobenzenes.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CP/C6CP01975G

Reference45 articles.

1. Flourine coupling constants

2. Contact Electron‐Spin Coupling of Nuclear Magnetic Moments

3. Conformation and substituent dependence of long-range hydrogen-hydrogen coupling over four bonds

4. Self‐Consistent Perturbation Theory. II. Nuclear‐Spin Coupling Constants

5. The “through-space” mechanism in spin spin coupling

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