What is special about silicon in functionalised organic semiconductors?-Reference-Cited by-同舟云学术

What is special about silicon in functionalised organic semiconductors?

Published:2021 Issue:16 Volume:2 Page:5415-5421
ISSN:2633-5409
Container-title:Materials Advances
language:en
Short-container-title:Mater. Adv.

Author:

Thorley Karl J.¹²^ORCID,Benford Micai³,Song Yang³,Parkin Sean R.¹^ORCID,Risko Chad¹²^ORCID,Anthony John E.¹²

Affiliation:

1. University of Kentucky, Department of Chemistry, Lexington, KY 40508, USA

2. University of Kentucky, Center for Applied Energy Research, Lexington, KY 40511, USA

3. Centre College, Department of Chemistry, Danville, KY 40422, USA

Abstract

Atomic substitution in sidechains of an organic semiconductor show these solubilizing groups are not simple spectators. Silicon is the most electron withdrawing group 14 element, increasing photostability and offering desirable crystal packing.

Funder

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Chemistry (miscellaneous)

Link

http://pubs.rsc.org/en/content/articlepdf/2021/MA/D1MA00447F

Reference21 articles.

1. Functionalized Pentacene: Improved Electronic Properties from Control of Solid-State Order

2. Bistetracene: An Air-Stable, High-Mobility Organic Semiconductor with Extended Conjugation

3. Triisopropylsilylethynyl-Functionalized Graphene-Like Fragment Semiconductors: Synthesis, Crystal Packing, and Density Functional Theory Calculations

4. Electron-Accepting 6,12-Diethynylindeno[1,2-b]fluorenes: Synthesis, Crystal Structures, and Photophysical Properties

5. Strongly exchange-coupled triplet pairs in an organic semiconductor

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