Green and effective synthesis of multisubstituted α-pyrones via K2CO3 catalyzed formal insertion of ketenimines into C(CO)–C bonds of 1,3-diketones-Reference-Cited by-同舟云学术

Green and effective synthesis of multisubstituted α-pyrones via K₂CO₃ catalyzed formal insertion of ketenimines into C(CO)–C bonds of 1,3-diketones

Published:2023 Issue:20 Volume:25 Page:8057-8067
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Luo Jian¹,Zhong Ai-Qing²,Qiu Jia-Hao¹,Liu Xiong-Wei³,Tian You-Ping³,Zhang Bao-Hua¹^ORCID,Chen Guo-Shu¹,Shu Wei⁴^ORCID,Liu Yun-Lin¹⁵^ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering, Guangzhou University, 230 Wai Huan Xi Road, Guangzhou, 510006, China

2. Guangdong Teachers College of Foreign Language and Arts, 463 Shougouling Road, Guangzhou, 510640, China

3. School of Pharmacy, Guizhou University of Traditional Chinese Medicine, Guiyang 550025, China

4. Shenzhen Grubbs Institute and Department of Chemistry, Southern University of Science and Technology, Shenzhen, 518055, China

5. Key Laboratory of Tropical Medicinal Resource Chemistry of Ministry of Education; Hainan Normal University, Hainan, Haikou 571158, China

Abstract

A green synthetic approach to prepare racemic or enantioenriched multisubstituted α-pyrones through the K2CO3-catalyzed formal C(CO)–C bond insertion reaction of ketenimines with 1,3-diketones was developed.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Guangdong Province

Hainan Normal University

Guangzhou Municipal Science and Technology Project

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/GC/D3GC02073H

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