Dynamic Pt–OH·H2O–Ag species mediate coupled electron and proton transfer for catalytic hydride reduction of 4-nitrophenol at the confined nanoscale interface

Author:

Ding Meng1,Shan Bing-Qian1,Peng Bo1,Zhou Jia-Feng1,Zhang Kun1234ORCID

Affiliation:

1. Shanghai Key Laboratory of Green Chemistry and Chemical Processes, College of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, China

2. Laboratoire de chimie, Ecole Normale Supérieure de Lyon, Institut de Chimie de Lyon, Université de Lyon, 46 Allée d’italie, 69364 Lyon cedex 07, France

3. Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng, 252059, Shandong, P. R. China

4. Institute of Eco-Chongming, Shanghai 202162, China

Abstract

Structural water molecules (SWs) dominated p band transient states for coupled electron and proton transfer on the bimetallic Pt–Ag supported silica catalysts for enhanced catalytic hydride reduction of 4-nitrophenol.

Funder

National Natural Science Foundation of China

Science and Technology Commission of Shanghai Municipality

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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