Pairwise semi-hydrogenation of alkyne to cis-alkene on platinum-tin intermetallic compounds

Author:

Pei Yuchen1234ORCID,Chen Minda1234ORCID,Zhong Xiaoliang567ORCID,Zhao Tommy Yunpu1894,Ferrer Maria-Jose1894,Maligal-Ganesh Raghu V.1234ORCID,Ma Tao101134ORCID,Zhang Biying1234,Qi Zhiyuan1234,Zhou Lin101134ORCID,Bowers Clifford R.1894,Liu Cong1213144ORCID,Huang Wenyu123410ORCID

Affiliation:

1. Department of Chemistry

2. Iowa State University

3. Ames

4. USA

5. Huazhong University of Science and Technology

6. Wuhan

7. China

8. University of Florida

9. Gainesville

10. Ames Laboratory

11. the U.S. Department of Energy

12. Chemical Sciences and Engineering Division

13. Argonne National Laboratory

14. Lemont

Abstract

Intermetallic PtSn nanoparticles leads to pairwise-hydrogenation of alkynes to the corresponding cis-alkenes, satisfying both high stereoselectivity and high chemoselectivity.

Funder

National Science Foundation

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

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