The unexpected photoelectrochemical activity of MAX phases: the role of oxide impurities

Author:

Sanna Michela1ORCID,Novčić Katarina A.1ORCID,Ng Siowwoon1ORCID,Černý Miroslav23,Pumera Martin145ORCID

Affiliation:

1. Future Energy and Innovation Laboratory, Central European Institute of Technology, Brno University of Technology, Purkyňova 123, 61200 Brno, Czech Republic

2. Central European Institute of Technology, Brno University of Technology, Technická 2, CZ-616 69 Brno, Czech Republic

3. Faculty of Mechanical Engineering, Brno University of Technology, Technická 2, CZ-616 69 Brno, Czech Republic

4. Faculty of Electrical Engineering and Computer Science, VSB–Technical University of Ostrava, 17. Listopadu 2172/15, 70800 Ostrava, Czech Republic

5. Department of Medical Research, China Medical University Hospital, China Medical University, No. 91 Hsueh-Shih Road, Taichung 40402, Taiwan

Abstract

Despite the absence of band gap calculated for MAX phases, the experimental analysis showed the crucial role that impurities play in the photoelectrochemical hydrogen generation, leading to better performances thanks to their intrinsic photoactivity.

Funder

Vysoké Učení Technické v Brně

Grantová Agentura České Republiky

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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