Synthesis and electronic structure analysis of the actinide allenylidenes, [{(NR2)3}An(CCCPh2)]− (An = U, Th; R = SiMe3)-Reference-Cited by-同舟云学术

Synthesis and electronic structure analysis of the actinide allenylidenes, [{(NR2)3}An(CCCPh2)]− (An = U, Th; R = SiMe3)

Published:2021 Issue:43 Volume:12 Page:14383-14388
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Kent Greggory T.¹^ORCID,Yu Xiaojuan²^ORCID,Wu Guang¹,Autschbach Jochen²^ORCID,Hayton Trevor W.¹^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry, University of California Santa Barbara, Santa Barbara, CA 93106, USA

2. Department of Chemistry, University at Buffalo, State University of New York, Buffalo, NY 14260, USA

Abstract

The actinide allenylidenes [{(NR2)3}An(CCCPh2)]− (An = U, Th, R = SiMe3) feature significant ligand-to-metal donation bonding and partial AnC double bond character.

Funder

Basic Energy Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC04666G

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3. The Nature of the UC Double Bond: Pushing the Stability of High-Oxidation-State Uranium Carbenes to the Limit

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