Probing the reactivity of pentaphenylborole with N–H, O–H, P–H, and S

Probing the reactivity of pentaphenylborole with N–H, O–H, P–H, and S–H bonds

Published:2016 Issue:24 Volume:45 Page:9902-9911
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Yruegas Sam¹²³⁴,Huang Kexuan¹²³⁴,Wilson David J. D.⁵⁶⁷⁸⁹,Dutton Jason L.⁵⁶⁷⁸⁹,Martin Caleb D.¹²³⁴

Affiliation:

1. Baylor University

2. Department of Chemistry and Biochemistry

3. Waco

4. USA

5. Department of Chemistry and Physics

6. La Trobe Institute for Molecular Science

7. La Trobe University

8. Melbourne

9. Australia

Abstract

The reactions of molecules containing E–H functionalities (E = Group 15 or 16 element) and pentaphenylborole were investigated revealing diverse outcomes.

Funder

Welch Foundation

Australian Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT00052E

Reference90 articles.

1. Synthesis of pentaphenylborole, a potentially antiaromatic system

2. Bora-aromatic systems. Part 8. The physical and chemical consequences of cyclic conjugation in boracyclopolyenes. The antiaromatic character of pentaarylboroles

3. Borole derivatives

4. Synthesis of boroles and their use in low-temperature Diels-Alder reactions with unactivated alkenes

5. Structural Evidence for Antiaromaticity in Free Boroles

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