Aryl(silyl)amino group stabilized hydridosilanediols: synthesis and characterization and use for preparation of alumino(hydrido)siloxanes-Reference-Cited by-同舟云学术

Aryl(silyl)amino group stabilized hydridosilanediols: synthesis and characterization and use for preparation of alumino(hydrido)siloxanes

Published:2016 Issue:15 Volume:45 Page:6709-6717
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Wang Xiaoping¹²³⁴⁵,Li Jiancheng¹²³⁴⁵,Chen Shimin¹²³⁴⁵,Liu Weiping⁶⁷⁸⁹,Ye Qingsong⁶⁷⁸⁹,Zhu Hongping¹²³⁴⁵

Affiliation:

1. State Key Laboratory of Physical Chemistry of Solid Surfaces

2. National Engineering Laboratory for Green Chemical Productions of Alcohols-Ethers-Esters

3. College of Chemistry and Chemical Engineering

4. Xiamen University

5. Xiamen

6. State Key Laboratory for Platinum Group Metals

7. Kunming Institute of Precious Metals

8. Kunming

9. China

Abstract

Alumino(hydrido)siloxane [RSi(H)O₂AlH(THF)]₂ (R = N(SiMe₂Ph)-2,6-iPr₂C₆H₃), prepared from the reaction of RSiH(OH)₂ and AlH₃·NMe₃ in THF under controlled temperature, shows an anchoring of the hydrido group on both the Si and Al atoms of the Si₂O₄Al₂ framework.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT00059B

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