Phosphine-functionalized NHC Ni(ii) and Ni(0) complexes: synthesis, characterization and catalytic properties

Author:

Rull S. G.12345ORCID,Rama R. J.6789,Álvarez E.1011129,Fructos M. R.12345,Belderrain T. R.12345ORCID,Nicasio M. C.6789ORCID

Affiliation:

1. Laboratorio de Catálisis Homogénea

2. Unidad Asociada al CSIC

3. CIQSO-Centro de Investigación en Química Sostenible and Departamento de Química

4. Universidad de Huelva

5. 21007-Huelva

6. Departamento de Química Inorgánica

7. Universidad de Sevilla

8. 41071-Sevilla

9. Spain

10. Instituto de Investigaciones Químicas

11. CSIC-Universidad de Sevilla

12. 41092-Sevilla

Abstract

Ni(ii) and Ni(0) complexes bearing chelating diphenylphosphine-functionalized NHC ligands have been prepared and characterized. Their catalytic behavior in various cross-coupling reactions has also been examined.

Funder

Ministerio de Economía y Competitividad

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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