Insight into the drastically different triplet lifetimes of BODIPY obtained by optical/magnetic spectroscopy and theoretical computations

Author:

Wang Zhijia12345ORCID,Toffoletti Antonio6789ORCID,Hou Yuqi12345ORCID,Zhao Jianzhang12345ORCID,Barbon Antonio6789ORCID,Dick Bernhard1011121314ORCID

Affiliation:

1. State Key Laboratory of Fine Chemicals

2. School of Chemical Engineering

3. Dalian University of Technology

4. Dalian 116024

5. China

6. Dipartimento di Scienze Chimiche

7. Università degli Studi di Padova

8. 35131 Padova

9. Italy

10. Lehrstuhl für Physikalische Chemie

11. Institut für Physikalische und Theoretische Chemie

12. Universität Regensburg

13. D-93053 Regensburg

14. Germany

Abstract

The electron spin polarization inversion and anisotropic decay of triplet substates explain the short triplet state lifetime of BODIPY derivatives.

Funder

Postdoctoral Research Foundation of China

National Natural Science Foundation of China

Fundamental Research Funds for the Central Universities

Dalian University of Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Reference69 articles.

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2. J. R. Lakowicz , Principles of fluorescence spectroscopy , Springer Science & Business Media , 2013

3. B. Valeur , Characteristics of fluorescence emission , Molecular Fluorescence: Principles and Applications , Wiley-VCH Verlag GmbH & Co. KGaA , 2012

4. Organic sensitizers from D–π–A to D–A–π–A: effect of the internal electron-withdrawing units on molecular absorption, energy levels and photovoltaic performances

5. Triarylamine: a promising core unit for efficient photovoltaic materials

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