Impact of morphology on polaron delocalization in a semicrystalline conjugated polymer

Author:

Steyrleuthner Robert12345ORCID,Zhang Yuexing678910,Zhang Lei1112131415,Kraffert Felix12345,Cherniawski Benjamin P.1112131415,Bittl Robert12345,Briseno Alejandro L.1112131415,Bredas Jean-Luc6789,Behrends Jan12345ORCID

Affiliation:

1. Freie Universität Berlin

2. Berlin Joint EPR Lab

3. Institut für Experimentalphysik

4. Berlin

5. Germany

6. King Abdullah University of Science & Technology

7. Solar & Photovoltaics Engineering Research Center

8. Thuwal 23955-6900

9. Saudi Arabia

10. Department of Chemistry

11. Department of Polymer Science and Engineering

12. Conte Research Center

13. University of Massachusetts

14. Amherst

15. USA

Abstract

We use spin resonant techniques to shed light on the delocalization length of polarons in a semicrystalline conjugated polymer and reveal how it directly depends on the thin film morphology.

Funder

National Science Foundation

Helmholtz Association

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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