Aluminum derivative peroxides in the (t-BuO)3Al–2t-BuOOH catalytic system as a source of electron-excited dioxygen: a quantum chemical study on a model-Reference-Cited by-同舟云学术

Aluminum derivative peroxides in the (t-BuO)3Al–2t-BuOOH catalytic system as a source of electron-excited dioxygen: a quantum chemical study on a model

Published:2016 Issue:98 Volume:6 Page:95542-95555
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Gadzhiev Oleg B.¹²³⁴⁵,Dodonov Victor A.¹²³⁴,Petrov Alexander I.⁶⁷⁸⁴⁹

Affiliation:

1. Department of Chemistry

2. N.I. Lobachevsky State University of Nizhny Novgorod

3. Nizhny Novgorod

4. Russia

5. G.G. Devyatykh Institute of Chemistry of High-Purity Substances

6. Institute of Non-Ferrous Metals and Materials Science

7. Siberian Federal University

8. Krasnoyarsk

9. Institute of Chemistry and Chemical Technology

Abstract

The t-BuOOH catalytic decomposition leads to reactive oxygen species including chemically activated and chemically excited (O₂(b¹Σ+g) and O₂(¹Δ_g)) dioxygen.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA21471A

Reference85 articles.

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2. Reactivity of Various Four-Coordinate Aluminum Alkyls towards Dioxygen: Evidence for Spatial Requirements in the Insertion of an Oxygen Molecule into the Al−C Bond

3. J. Lewiński and A. H.Wheatley, in Modern Organoaluminum Reagents, ed. S. Woodward and S. Dagorne, Springer, Berlin-Heidelberg, Germany, 2013, vol. 41, ch. 55, pp. 1–58

4. Chemiluminescence in the oxidation of organoaluminum compounds by oxygen

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