Metallophilic Au(i)⋯M(i) interactions (M = Tl, Ag) in heteronuclear complexes with 1,4,7-triazacyclononane: structural features and optical properties
Author:
Affiliation:
1. Departamento de Química
2. Centro de Investigación en Síntesis Química (CISQ)
3. Universidad de la Rioja
4. 26004-Logroño
5. Spain
6. Dipartimento di Scienze Chimiche e Geologiche
7. Università degli Studi di Cagliari
8. 09042-Monserrato
9. Italy
Abstract
New heterometallic Au(i)–M (M = Ag(i) or Tl(i)) complexes show macrocylic ligand (TACN)-directed emissive properties.
Funder
Fondazione di Sardegna
Secretaría de Estado de Investigación, Desarrollo e Innovación
Ministerio de Economía y Competitividad
European Regional Development Fund
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT01902J
Reference82 articles.
1. A luminescent heterometallic AuI⋯ CuIcomplex. Spectroscopic properties and crystal structures of [Au(PPh3)(C7H5N2)] and [(Au(PPh3)(µ-C7H5N2)Cu-(µ-C7H5N2)}2](C7H5N2= 7-azaindolate)
2. Copper(i)-assisted red-shifted phosphorescence in Au(i)⋯Cu(i) heteropolynuclear complexes
3. Unsupported Au(i)⋯Cu(i) interactions: influence of nitrile ligands and aurophilicity on the structure and luminescence
4. Luminescent Characterization of Solution Oligomerization Process Mediated Gold−Gold Interactions. DFT Calculations on [Au2Ag2R4L2]n Moieties
5. Temperature-assisted formation of reversible metallophilic Au–Ag interaction arrays
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