Synthesis and (spectro)electrochemistry of mixed-valent diferrocenyl–dihydrothiopyran derivatives-Reference-Cited by-同舟云学术

Synthesis and (spectro)electrochemistry of mixed-valent diferrocenyl–dihydrothiopyran derivatives

Published:2015 Issue:13 Volume:44 Page:6268-6276
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Kowalski Konrad¹²³⁴⁵,Karpowicz Rafał¹²³⁴⁵,Mlostoń Grzegorz¹⁶³⁴⁵,Miesel Dominique⁷⁸⁹¹⁰¹¹,Hildebrandt Alexander⁷⁸⁹¹⁰¹¹,Lang Heinrich⁷⁸⁹¹⁰¹¹,Czerwieniec Rafał¹²¹³¹⁴¹⁵,Therrien Bruno⁹¹⁶¹⁷¹⁸

Affiliation:

1. Faculty of Chemistry

2. Department of Organic Chemistry

3. University of Łódź

4. PL-91403 Łódź

5. Poland

6. Department of Organic and Applied Chemistry

7. Technische Universität Chemnitz

8. Faculty of Natural Sciences

9. Institute of Chemistry

10. Department of Inorganic Chemistry

11. D-09107 Chemnitz

12. Universität Regensburg

13. Institut für Physikalische und Theoretische Chemie

14. D-93040 Regensburg

15. Germany

16. University of Neuchatel

17. CH-2000 Neuchatel

18. Switzerland

Abstract

Cationic cyclic diferrocenyl–methane complexes display characteristic IVCT absorptions. These spectral features result from effective “through space” electronic communication between the metal centre in these mixed-valent dimetallic species.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT00246J

Reference82 articles.

1. Mixed Valency at the Nearly Delocalized Limit: Fundamentals and Forecast

2. Intervalence Charge Transfer (IVCT) in Trinuclear and Tetranuclear Complexes of Iron, Ruthenium, and Osmium

3. Magnetic perturbation of the redox potentials of localized and delocalized mixed-valence complexes

4. Ferrocenyl-Terminated Redox Stars: Synthesis and Electrostatic Effects in Mixed-Valence Stabilization

5. Electronic communication in heterobinuclear organometallic complexes through unsaturated hydrocarbon bridges

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