Gold-catalyzed [4+3]- and [4+2]-annulations of 3-en-1-ynamides with isoxazoles via novel 6π-electrocyclizations of 3-azahepta trienyl cations

Author:

Giri Sovan Sundar1234,Liu Rai-Shung1234ORCID

Affiliation:

1. Department of Chemistry

2. National Tsing-Hua University

3. Hsinchu

4. Republic of China

Abstract

Gold-catalysed [4+3]- and [4+2]-annulations of 3-substituted 3-en-1-ynamides with isoxazoles were achieved with Au(i) and Au(i)/Zn(ii) catalysts respectively.

Funder

Ministry of Education

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Reference56 articles.

1. S. Sankararaman , in Pericyclic Reactions-A Textbook. Reactions, Applications and Theory , Wiley-VCH , New York , 2005 , ch. 6, pp. 393–398

2. Biosynthetic and Biomimetic Electrocyclizations

3. Aromaticity in transition structures

4. Recent Advances on the Application of Electrocyclic Reactions in Complex Natural Product Synthesis

5. 1,5-Dipolar cyclizations

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