The contrarotational fluxionality of [3,3-(PMe2Ph)2-closo-3,1,2-PtC2B9H11] and related species-Reference-Cited by-同舟云学术

The contrarotational fluxionality of [3,3-(PMe2Ph)2-closo-3,1,2-PtC2B9H11] and related species

Published:2015 Issue:20 Volume:44 Page:9620-9629
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Kennedy Robert D.¹²³⁴⁵,Kennedy John D.⁶⁷⁸⁹¹⁰

Affiliation:

1. Department of Chemistry and Biochemistry

2. University of California

3. Los Angeles, USA

4. Department of Chemistry

5. Northwestern University

6. School of Chemistry

7. University of Leeds

8. Leeds, UK LS2 9JT

9. Institute of Inorganic Chemistry

10. Academy of Sciences of the Czech Republic

Abstract

DFT calculations allied with experimental crystallographic and NMR results elucidate the energetics and the geometrical and ¹¹B nuclear shielding changes in the contrarotational fluxionality of [3,3-(PMe₂Ph)₂-closo-3,1,2-PtC₂B₉H₁₁] and confirm the incidence and identities of two stable rotational conformers.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT00984G

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