Structural and mechanistic studies of excitation- and temperature-tunable multicolor luminescence of triarylborane

Author:

Xie Yangbin1,Dai Songshan1,Wang Yue1,Wang Xi1,Sun Ying1,Ju Zhenghua1,Fang Ran2ORCID,Zhang Baoxin1ORCID,Wu Jincai1ORCID,Zhang Xiaoxiang3,Pan Xiaobo1ORCID

Affiliation:

1. State Key Laboratory of Applied Organic Chemistry (Lanzhou University), Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, People's Republic of China

2. College of Chemistry and Chemical Engineering, Shaanxi University of Science and Technology, Xi'an 710021, People's Republic of China

3. Lixiahe Agricultural Research Institute of Jiangsu Province, Yangzhou, Jiangsu 225007, China

Abstract

Racemate (rac-1) and conglomerate (cong-1) crystals show different phosphorescence behaviour.Rac-1 is a strong excitation-wavelength-tunable photoluminescent material; cong-1 exhibits white-light emission upon temperature change with a CIE 1931 coordinate of (0.33, 0.31).

Funder

National Natural Science Foundation of China

Natural Science Foundation of Gansu Province

Natural Science Foundation of Jiangsu Province

Special Fund Project of Guiding Scientific and Technological Innovation Development of Gansu Province

Higher Education Discipline Innovation Project

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

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