Mechanisms for dehydrogenation and hydrogenation of N-heterocycles using PNP-pincer-supported iron catalysts: a density functional study-Reference-Cited by-同舟云学术

Mechanisms for dehydrogenation and hydrogenation of N-heterocycles using PNP-pincer-supported iron catalysts: a density functional study

Published:2016 Issue:38 Volume:45 Page:14965-14978
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Sawatlon Boodsarin¹²³⁴⁵,Surawatanawong Panida¹²³⁴⁵

Affiliation:

1. Department of Chemistry and Center of Excellence for Innovation in Chemistry

2. Faculty of Science

3. Mahidol University

4. Bangkok 10400

5. Thailand

Abstract

The bifunctionality of Fe-PNP plays a role in stabilizing the ion-pair complex in the dehydrogenation via a hydrogen bonding and a C–H agostic interaction.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT02431A

Reference66 articles.

1. Catalytic Dehydrogenation of Light Alkanes on Metals and Metal Oxides

2. Dehydrogenation and Related Reactions Catalyzed by Iridium Pincer Complexes

3. Dehydrogenation of polycyclic hydroaromatic compounds

4. Robust cyclometallated Ir(iii) catalysts for the homogeneous hydrogenation of N-heterocycles under mild conditions

5. Iridium-Catalyzed Hydrogenation of N-Heterocyclic Compounds under Mild Conditions by an Outer-Sphere Pathway

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