Long-lived, near-IR emission from Cr(<scp>iii</scp>) under ambient conditions-Reference-Cited by-同舟云学术

Long-lived, near-IR emission from Cr(iii) under ambient conditions

Published:2022 Issue:38 Volume:58 Page:5733-5736
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Sawicka Natalia¹,Craze Chloe J.¹,Horton Peter N.²,Coles Simon J.²^ORCID,Richards Emma¹^ORCID,Pope Simon J. A.¹^ORCID

Affiliation:

1. School of Chemistry, Main Building, Cardiff University, Cardiff CF10 3AT, Cymru/Wales, UK

2. UK National Crystallographic Service, Chemistry, Faculty of Natural and Environmental Sciences, University of Southampton, Highfield, Southampton, SO17 1BJ, England, UK

Abstract

[Cr(N^N^N)2]PF6 complexes that incorporate both pyridyl and isoindoline donors possess physical properties that lead to the observation of near-IR phosphorescence (928–949 nm) under aerated solvent conditions at room temperature.

Funder

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC01434C

Reference32 articles.

1. Chromium complexes for luminescence, solar cells, photoredox catalysis, upconversion, and phototriggered NO release

2. Luminescent complexes made from chelating isocyanide ligands and earth-abundant metals

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4. Heteroleptic trivalent chromium in coordination chemistry: Novel building blocks for addressing old challenges in multimetallic luminescent complexes

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