Turn on of sky-blue thermally activated delayed fluorescence and circularly polarized luminescence (CPL) via increased torsion by a bulky carbazolophane donor

Author:

Sharma Nidhi12341,Spuling Eduard5678ORCID,Mattern Cornelia M.5678,Li Wenbo191034,Fuhr Olaf1112138ORCID,Tsuchiya Youichi1415161718ORCID,Adachi Chihaya1415161718ORCID,Bräse Stefan567819ORCID,Samuel Ifor D. W.191034ORCID,Zysman-Colman Eli1234ORCID

Affiliation:

1. Organic Semiconductor Centre

2. EaStCHEM School of Chemistry

3. University of St Andrews

4. UK

5. Institute of Organic Chemistry (IOC)

6. Karlsruhe Institute of Technology (KIT)

7. 76131 Karlsruhe

8. Germany

9. SUPA

10. School of Physics and Astronomy

11. Institute of Nanotechnology (INT) and Karlsruhe Nano-Micro Facility (KNMF)

12. Karlsruhe Institute of Technology

13. D-76344 Eggenstein-Leopoldshafen

14. Center for Organic Photonics and Electronics Research (OPERA)

15. Kyushu University

16. Fukuoka 819-0395

17. Japan

18. JST

19. Institute of Toxicology and Genetics (ITG)

Abstract

The carbazolophane (Czp) donor unit is introduced to the design pool of donors in TADF emitters.

Funder

Engineering and Physical Sciences Research Council

Japan Society for the Promotion of Science

University of St Andrews

Japan Science and Technology Agency

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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