Experimental evidence of co-existence of equilibrium and nonequilibrium in two-glass-transition miscible mixtures

Author:

Jin Xiao12345ORCID,Guo Yuxing12345,Tu Wenkang12345,Feng Shidong12345,Liu Yingdan12345ORCID,Blochowicz Thomas6789,Wang Li-Min12345

Affiliation:

1. State Key Lab of Metastable Materials Science and Technology, and College of Materials Science and Engineering

2. Yanshan University

3. Qinhuangdao

4. Hebei

5. China

6. Institut für Festkörperphysik

7. Technische Universität Darmstadt

8. 64289 Darmstadt

9. Germany

Abstract

Two glass-transitions have been observed in some miscible molecular mixtures with notable differences in geometry or chemistry of constituents. Ageing between the high and low glass transitions confirm the co-existence of nonequilibrium and equilibrium states in the regions.

Funder

National Natural Science Foundation of China

National Basic Research Program of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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