Single- and double-bridged PNP ligands in chromium-catalysed ethylene oligomerisation-Reference-Cited by-同舟云学术

Single- and double-bridged PNP ligands in chromium-catalysed ethylene oligomerisation

Published:2022 Issue:14 Volume:12 Page:4544-4551
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Lo Quintin¹,Pye Dominic¹,Gesslbauer Sami¹,Sim Ying²,García Felipe²³^ORCID,White Andrew J. P.¹,Britovsek George J. P.¹^ORCID

Affiliation:

1. Department of Chemistry, Imperial College London, Molecular Sciences Research Hub, White City Campus, 82 Wood Lane, London, W12 0BZ, UK

2. Division of Chemistry & Biological Chemistry, NTU, 21 Nanyang Link, 637371, Singapore

3. Departamento de Química Orgánica e Inorgánica, Facultad de Química, Universidad de Oviedo, Julián Claveria 8, 33006 Oviedo, Spain

Abstract

Chromium catalysts with diazaphospholane ligands have shown good activities and selectivities for ethylene tri- and tetramerisation. Oligomerisations with a doubly N-bridged cyclodiphosphazane result in a Schulz–Flory distribution of α-olefins.

Funder

UK Catalysis Hub

Fundación para el Fomento en Asturias de la Investigación Científica Aplicada y la Tecnología

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CY/D2CY00550F

Reference65 articles.

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4. The Mathematics of Ethylene Oligomerisation and Polymerisation

5. Selective ethylene oligomerization: Recent advances in chromium catalysis and mechanistic investigations

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