Formation of the intermetalloid cluster [AgSn18]7− – the reactivity of coinage metal NHC compounds towards [Sn9]4−-Reference-Cited by-同舟云学术

Formation of the intermetalloid cluster [AgSn18]7− – the reactivity of coinage metal NHC compounds towards [Sn9]4−

Published:2017 Issue:18 Volume:46 Page:5796-5800
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Geitner F. S.¹²³⁴,Klein W.⁵²³⁴,Fässler T. F.⁵²³⁴^ORCID

Affiliation:

1. WACKER-Institute for Silicon Chemistry and Department of Chemistry

2. Technische Universität München Lichtenbergstraße 4

3. 85747 Garching/München

4. Germany

5. Department of Chemistry

Abstract

A series of novel polyanionic coinage metal NHC Zintl clusters [NHC^DippM(η⁴-Sn₉)]³⁻ are obtained from the reaction of [Sn₉]⁴⁻ with NHC^DippMCl (M: Cu, Ag, Au; Dipp: diisopropylphenyl) in liquid ammonia. For M = Ag a larger intermetalloid Ag-bridged nonastannide dimer [(η⁴-Sn₉)Ag(η¹-Sn₉)]⁷⁻ forms.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT00754J

Reference33 articles.

1. Endohedral Zintl Ions: Intermetalloid Clusters

2. Understanding of multimetallic cluster growth

3. Step-by-Step Synthesis of the Endohedral Stannaspherene [Ir@Sn12]3−via the Capped Cluster Anion [Sn9Ir(cod)]3−

4. Zintl Ions, Cage Compounds, and Intermetalloid Clusters of Group 14 and Group 15 Elements

5. Chemistry of Deltahedral Zintl Ions

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