A cobalt arylphosphonate MOF – superior stability, sorption and magnetism

Author:

Zorlu Yunus1234ORCID,Erbahar Doğan56789,Çetinkaya Ahmet10111294,Bulut Aysun123413,Erkal Turan S.14151617,Yazaydin A. Ozgur14151617ORCID,Beckmann Jens1819202122ORCID,Yücesan Gündoğ23242522ORCID

Affiliation:

1. Department of Chemistry

2. Gebze Technical University

3. Gebze

4. Turkey

5. Dogus University

6. Fac. of Engineering

7. Dept. of Mechanical Eng. Acibadem

8. Kadikoy

9. Istanbul

10. Department of Bioengineering

11. Yildiz Technical University

12. Esenler

13. School of Pharmacy

14. Department of Chemical Engineering

15. University College London

16. London WC1E 7JE

17. UK

18. Institut für Anorganische Chemie und Kristallographie

19. Universität Bremen

20. Leobener Straße

21. 28359 Bremen

22. Germany

23. Lebensmittelchemie und Toxikologie

24. Technische Universität Berlin

25. Berlin

Abstract

We report a novel metal organic framework (MOF) based on a cobalt arylphosphonate, namely, [Co2(H4-MTPPA)]·3NMP·H2O (1·3NMP·H2O), which was prepared solvothermically from the tetrahedral linker tetraphenylmethane tetrakis-4-phosphonic acid (H8-MTPPA) and CoSO4·7H2O in N-methyl-2-pyrrolidone (NMP).

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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