One-pot catalytic asymmetric borylation of unsaturated aldehyde-derived imines; functionalisation to homoallylic boronate carboxylate ester derivatives-Reference-Cited by-同舟云学术

One-pot catalytic asymmetric borylation of unsaturated aldehyde-derived imines; functionalisation to homoallylic boronate carboxylate ester derivatives

Published:2015 Issue:18 Volume:13 Page:5122-5130
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Pujol Alba¹²³⁴⁵,Calow Adam D. J.¹²³⁴⁵,Batsanov Andrei S.¹²³⁴⁵,Whiting Andrew¹²³⁴⁵

Affiliation:

1. Centre for Sustainable Chemical Processes

2. Department of Chemistry

3. Durham University

4. Durham

5. UK

Abstract

The β-borylation reaction of α,β-unsaturated aldehyde-derived imines, formed in situ, has been studied using a one-pot methodology, as a route to homoallylic boronates through the β-boryl aldehydes.

Funder

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/OB/C4OB02657H

Reference29 articles.

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4. Platinum catalysed 1,4-diboration of α,β-unsaturated ketones

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