Fast kinetics studies of the Lewis acid–base complexation of transient stannylenes with σ- and π-donors in solution

Author:

Duffy Ian R.1234ORCID,Leigh William J.1234ORCID

Affiliation:

1. Department of Chemistry & Chemical Biology

2. McMaster University

3. Hamilton

4. Canada L8S 4M1

Abstract

The complexation of SnMe2 and SnPh2 with a variety of σ- and π-donors and its effects on their dimerization reactions has been studied by laser flash photolysis and DFT methods, and compared to reported data for the Si and Ge homologues.

Funder

Natural Sciences and Engineering Research Council of Canada

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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