The gold(i)⋯lead(ii) interaction: a relativistic connection-Reference-Cited by-同舟云学术

The gold(i)⋯lead(ii) interaction: a relativistic connection

Published:2015 Issue:3 Volume:6 Page:2022-2026
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Echeverría Raquel¹²³⁴⁵,López-de-Luzuriaga José M.¹²³⁴⁵,Monge Miguel¹²³⁴⁵,Olmos M. Elena¹²³⁴⁵

Affiliation:

1. Departamento de Química

2. Universidad de La Rioja

3. Centro de Investigación en Síntesis Química (CISQ)

4. Complejo Científico-Tecnológico

5. 26004-Logroño

Abstract

The heteronuclear complex [Pb{HB(pz)₃}Au(C₆Cl₅)₂] is a blue emitter in the solid state and displays an unprecedented and unsupported Au(i)⋯Pb(ii) contact.Ab initiocalculations show a very strong metallophilic interaction that is greatly influenced by relativistic effects.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/SC/C4SC03680H

Reference23 articles.

1. Relativistic Effects in Chemistry: More Common Than You Thought

2. Relativity and the periodic system of elements

3. Aurophilic interactions as a subject of current research: an up-date

4. Relativistic effects in homogeneous gold catalysis

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