Coordination of arenes and phosphines by charge separated alkaline earth cations-Reference-Cited by-同舟云学术

Coordination of arenes and phosphines by charge separated alkaline earth cations

Published:2018 Issue:36 Volume:47 Page:12684-12693
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Garcia Lucia¹²³⁴,Anker Mathew D.¹²³⁴,Mahon Mary F.¹²³⁴,Maron Laurent⁵⁶⁷⁸⁹,Hill Michael S.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University of Bath

3. Bath

4. UK

5. Université de Toulouse et CNRS

6. INSA

7. UPS

8. UMR 5215

9. LPCNO

Abstract

Generation of ‘naked’ β-diketiminato magnesium and calcium cations allows the isolation of benzene, toluene, 1,4-difluorobenzene and terminal phosphine adducts.

Funder

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT03124J

Reference70 articles.

1. Cation-π Interactions in Chemistry and Biology: A New View of Benzene, Phe, Tyr, and Trp

2. The Cation−π Interaction

3. Cation−π Interaction: Its Role and Relevance in Chemistry, Biology, and Material Science

4. Gas-Phase Reactions of hydrated alkaline earth metal ions, M2+(H2O)n (M = Mg, Ca, Sr, Ba and n = 4–7), with benzene

5. Is the Cation/π Interaction in Alkaline-Earth-Metal Dication/Benzene Complexes a Covalent Interaction?

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