Efficient Mukaiyama aldol reaction in water with TiO4 tetrahedra on a hydrophobic mesoporous silica surface-Reference-Cited by-同舟云学术

Efficient Mukaiyama aldol reaction in water with TiO4 tetrahedra on a hydrophobic mesoporous silica surface

Published:2014 Issue:88 Volume:50 Page:13473-13476
ISSN:1359-7345
Container-title:Chem. Commun.
language:en
Short-container-title:Chem. Commun.

Author:

Shintaku Hiroshi¹²³,Nakajima Kiyotaka¹²³⁴⁵,Kitano Masaaki⁶²³,Hara Michikazu¹²³⁴⁷

Affiliation:

1. Materials and Structures Laboratory

2. Tokyo Institute of Technology

3. Yokohama 226-8503, Japan

4. Japan Science and Technology (JST) Agency

5. PRESTO

6. Materials Research Center for Elemental Strategy

7. Kawaguchi 332-0012, Japan

Abstract

A new heterogeneous catalyst, hydrophobic TiO₄-deposited mesoporous silica, exhibited high catalytic performance as a reusable catalyst for the Mukaiyama-aldol condensation in water without a surfactant.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2014/CC/C4CC05711B

Reference46 articles.

1. NEW ALDOL TYPE REACTION

2. New cross-aldol reactions. Reactions of silyl enol ethers with carbonyl compounds activated by titanium tetrachloride

3. The Impact of the Mukaiyama Aldol Reaction in Total Synthesis

4. Lewis Base Catalysis of the Mukaiyama Directed Aldol Reaction: 40 Years of Inspiration and Advances

5. A Catalytic Aldol Reaction between Ketene Silyl Acetals and Aldehydes Promoted by Lithium Amide under Non-acidic Conditions

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