The impact of charge transfer and structural disorder on the thermoelectric properties of cobalt intercalated TiS2

Author:

Guélou Gabin1234,Vaqueiro Paz1234,Prado-Gonjal Jesús1234,Barbier Tristan5678,Hébert Sylvie5678,Guilmeau Emmanuel5678,Kockelmann Winfried91011124,Powell Anthony V.1234

Affiliation:

1. Department of Chemistry

2. University of Reading

3. Reading RG6 6AD

4. UK

5. Laboratoire CRISMAT

6. UMR6508 CNRS ENSICAEN

7. 14050 Caen Cedex 4

8. France

9. STFC

10. Rutherford Appleton Laboratory

11. ISIS Facility

12. Didcot OX11 0QX

Abstract

The thermoelectric figure of merit of TiS2 is increased by 25% through the intercalation of low levels of cobalt due to an increased electrical conductivity, arising from charge transfer, and a reduced thermal conductivity resulting from disorder.

Funder

European Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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