Effects of preorganization in the chelation of UO22+by hydroxamate ligands: cyclic PIPO−vs.linear NMA−-Reference-Cited by-同舟云学术

Effects of preorganization in the chelation of UO22+by hydroxamate ligands: cyclic PIPO−vs.linear NMA−

Published:2018 Issue:10 Volume:42 Page:7765-7779
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Sornosa-Ten Alejandra¹²³⁴⁵,Jewula Pawel¹²³⁴⁵^ORCID,Fodor Tamas¹²³⁴⁵,Brandès Stéphane¹²³⁴⁵^ORCID,Sladkov Vladimir⁶⁷³⁸⁹^ORCID,Rousselin Yoann¹²³⁴⁵^ORCID,Stern Christine¹²³⁴⁵^ORCID,Chambron Jean-Claude¹²³⁴⁵^ORCID,Meyer Michel¹²³⁴⁵^ORCID

Affiliation:

1. Institut de Chimie Moléculaire de l'Université de Bourgogne (ICMUB)

2. UMR 6302

3. CNRS

4. Université de Bourgogne – Franche-Comté

5. 21078 Dijon Cedex

6. Institut de Physique Nucléaire d'Orsay (IPNO)

7. UMR 8608

8. Université Paris Sud

9. 91406 Orsay Cedex

Abstract

Thanks to preorganization, 1,2-PIPOH, the six-membered ring cyclic hydroxamic acid, binds uranyl six times more strongly than its linear, methyl-substituted homolog (NMAH).

Funder

Centre National de la Recherche Scientifique

European Regional Development Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/NJ/C8NJ00166A

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