A reusable CuII based metal–organic framework as a catalyst for the oxidation of olefins

Author:

Cancino Patricio12343,Paredes-García Verónica56343,Aguirre Pedro123,Spodine Evgenia12343

Affiliation:

1. Facultad de Ciencias Químicas y Farmacéuticas

2. Universidad de Chile

3. Santiago, Chile

4. Centro para el Desarrollo de Nanociencia y Nanotecnología (CEDENNA)

5. Departamento de Ciencias Químicas

6. Universidad Andres Bello

Abstract

The metal–organic framework [Cu2(bipy)2(btec)] was used as a heterogeneous catalyst in the liquid phase oxidation of styrene and cyclohexene with tert-butylhydroperoxide (TBHP) as the oxidant either in water–dichloroethane or n-decane medium.

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Reference48 articles.

1. R. A. Sheldon and J. K.Kochi , Metal Complex Catalyzed Oxidation of Organic Compounds , Academic Press , New York , 1981

2. G. Cainelli and G.Cardillo , Chromium Oxidation in Organic Chemistry , Springer-Verlag , New York , 1984

3. J. I. Kroschwitz and K.Othmer , Encyclopedia of Chemical Technology Wiley-Interscience , New York , 1992

4. F. Ullmann , Ullmann's Encyclopedia of Industrial Chemistry , Wiley-VCH, Verlag , Weinheim, Germany , 2003

5. Epoxidation of olefins on M-SiO2 (M=Ti, Fe, V) catalysts with highly isolated transition metal ions prepared by ion beam implantation

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