Field-induced single-ion magnet based on a quasi-octahedral Co(ii) complex with mixed sulfur–oxygen coordination environment-Reference-Cited by-同舟云学术

Field-induced single-ion magnet based on a quasi-octahedral Co(ii) complex with mixed sulfur–oxygen coordination environment

Published:2021 Issue:39 Volume:50 Page:13815-13822
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Korchagin D. V.¹^ORCID,Gureev Ya. E.¹²,Yureva E. A.¹^ORCID,Shilov G. V.¹^ORCID,Akimov A. V.¹^ORCID,Misochko E. Ya.¹^ORCID,Morgunov R. B.¹,Zakharov K. V.²,Vasiliev A. N.²³^ORCID,Palii A. V.¹⁴^ORCID,Lohmiller T.⁵^ORCID,Holldack K.⁶^ORCID,Aldoshin S. M.¹^ORCID

Affiliation:

1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1, Acad. Semenov Av., Chernogolovka, Russian Federation, 142432

2. M.V. Lomonosov Moscow State University, Moscow 119991, Russia

3. National University of Science and Technology “MISiS”, Moscow, 119049, Russia

4. Institute of Applied Physics, Academy of Sciences of Moldova, Kishinev, Moldova

5. EPR4Energy Joint Lab, Department Spins in Energy Conversion and Quantum Information Science, Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, 12489 Berlin, Germany

6. Institut für Methoden und Instrumentierung der Forschung mit Synchrotronstrahlung, Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, 12489 Berlin, Germany

Abstract

Novel (pipH2)[Co(TDA)2] is a rare example of a quasi-octahedral Co(ii) complex with mixed sulfur-oxygen environment exhibiting strong “easy-plane” type magnetic anisotropy and demonstrating field-induced single-ion magnet (SIM) behavior.

Funder

Ministry of Science and Higher Education of the Russian Federation

National University of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT02413B

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