Molecular modulation of nickel–salophen organic frameworks enables the selective photoreduction of CO2 at varying concentrations

Author:

Yu Xiaohan12,Sun Mingzi3ORCID,Yan Tianran12,Jia Lin12,Chu Mingyu12,Zhang Liang12ORCID,Huang Wei12,Huang Bolong34ORCID,Li Yanguang125ORCID

Affiliation:

1. Institute of Functional Nano & Soft Materials (FUNSOM), Soochow University, Suzhou, 215123, China

2. Jiangsu Key Laboratory for Advanced Negative Carbon Technologies, Soochow University, Suzhou 215123, China

3. Department of Applied Biology and Chemical Technology, The Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong SAR 999077, China

4. Research Centre for Carbon-Strategic Catalysis, The Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong SAR 999077, China

5. Macao Institute of Materials Science and Engineering (MIMSE), MUST-SUDA Joint Research Center for Advanced Functional Materials, Macau University of Science and Technology, Taipa 999078, Macau SAR, China

Abstract

Metal–salophen organic frameworks with dispersed metal centers and precise coordination environments were synthesized. The optimal sample exhibited great photocatalytic activity and near-unity CO selectivity over a wide range of CO2 concentrations.

Funder

National Key Research and Development Program of China

National Natural Science Foundation of China

Research Grants Council, University Grants Committee

Natural Science Foundation of Jiangsu Province

Major Basic Research Project of the Natural Science Foundation of the Jiangsu Higher Education Institutions

Macau University of Science and Technology Foundation

Hong Kong Polytechnic University

Shenzhen Fundamental Research Program

Natural Science Foundation of Guangdong Province

Publisher

Royal Society of Chemistry (RSC)

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