Defect engineering of polyethylene-like polyphosphoesters: solid-state NMR characterization and surface chemistry of anisotropic polymer nanoplatelets

Author:

Markwart Jens C.123,Suraeva Oksana123,Haider Tobias123,Lieberwirth Ingo123ORCID,Graf Robert123ORCID,Wurm Frederik R.12345ORCID

Affiliation:

1. Max Planck Institute for Polymer Research

2. 55128 Mainz

3. Germany

4. “Sustainable Polymer Chemistry”

5. MESA+ Institute for Nanotechnology

Abstract

Polyethylene-like polyphosphoesters crystallized from dilute solution into anisotropic nanoplatelets. As proven by solid-state NMR, the phosphate groups are expelled to the surface and on-surface chemistry was conducted leaving the crystals intact.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

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