Betti base derived P-stereogenic phosphine-diamidophosphite ligands with a single atom spacer and their application in asymmetric catalysis-Reference-Cited by-同舟云学术

Betti base derived P-stereogenic phosphine-diamidophosphite ligands with a single atom spacer and their application in asymmetric catalysis

Published:2022 Issue: Volume: Page:
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Chakrabortty Soumyadeep¹^ORCID,Konieczny Katharina¹,Müller Bernd H.¹,Spannenberg Anke¹,Kamer Paul C. J.¹^ORCID,de Vries Johannes G.¹^ORCID

Affiliation:

1. Leibniz−Institut für Katalyse e.V., Albert-Einstein-Straße 29a, 18059 Rostock, Germany

Abstract

Small bite-angle P-chirogenic PNP ligands have been synthesized stereo-selectively and employed in Rh-catalyzed asymmetric hydrogenation and Pd-catalyzed asymmetric allylic substitution resulting in moderate to excellent enantioselectivities.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CY/D1CY02017J

Reference32 articles.

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4. Bite angle effects of diphosphines in C–C and C–X bond forming cross coupling reactions

5. Ligand Bite Angle Effects in Metal-catalyzed C−C Bond Formation

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