Compact accumulation of superatomic silver nanoclusters with an octahedral Ag<sub>6</sub> core ligated by trithiane-Reference-Cited by-同舟云学术

Compact accumulation of superatomic silver nanoclusters with an octahedral Ag₆ core ligated by trithiane

Published:2022 Issue:29 Volume:14 Page:10321-10326
ISSN:2040-3364
Container-title:Nanoscale
language:en
Short-container-title:Nanoscale

Author:

Cheng Xun¹,Zhong Rui-Ru²,Yuan Shang-Fu²^ORCID,Guan Zong-Jie³^ORCID,Liu Kuan-Guan¹^ORCID

Affiliation:

1. School of Materials and New Energy, Ningxia Key Laboratory of Photovoltaic Materials, Ningxia University, Yin-Chuan 750021, PR China

2. College of Chemistry and Materials Science and Guangdong Provincial Key Laboratory of Functional Supramolecular Coordination Materials and Applications, Jinan University, Guangzhou, 510632, P. R. China

3. College of Chemistry and Chemical Engineering, Hunan University, Changsha, 410082, P. R. China

Abstract

Two superatomic solids, a bi-cluster compound, [Ag6(3S)4(OTf)4][Ag6(3S)4(CCtBu)4](OTf)2 [Ag6(0)·Ag6(i)], and a homologous nanocluster, [Ag6(3S)4(tfa)4] (Ag6), have been described here, which are both close-packed in the crystal lattice with the ligation of trithiane.

Funder

Natural Science Foundation of Ningxia Province

State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

Link

http://pubs.rsc.org/en/content/articlepdf/2022/NR/D2NR02411J

Reference36 articles.

1. Cocrystallization of Atomically Precise Nanoclusters