Sodium cationization can disrupt the intramolecular hydrogen bond that mediates the sunscreen activity of oxybenzone-Reference-Cited by-同舟云学术

Sodium cationization can disrupt the intramolecular hydrogen bond that mediates the sunscreen activity of oxybenzone

Published:2020 Issue:35 Volume:22 Page:19522-19531
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Berenbeim Jacob A.¹²³⁴^ORCID,Wong Natalie G. K.¹²³⁴^ORCID,Cockett Martin C. R.¹²³⁴,Berden Giel⁵⁶⁷⁸⁹^ORCID,Oomens Jos⁵⁶⁷⁸⁹^ORCID,Rijs Anouk M.⁵⁶⁷⁸⁹^ORCID,Dessent Caroline E. H.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University of York

3. Heslington

4. UK

5. Radboud University

6. Institute for Molecules and Materials

7. FELIX Laboratory

8. Nijmegen

9. The Netherlands

Abstract

Complexation with a sodium cation breaks the intramolecular hydrogen bond of oxybenzone, compromising its ability to act as an effective UV filter.

Funder

Horizon 2020 Framework Programme

Leverhulme Trust

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CP/D0CP03152F

Reference57 articles.

1. Applications of ultrafast spectroscopy to sunscreen development, from first principles to complex mixtures

2. Photoprotection: extending lessons learned from studying natural sunscreens to the design of artificial sunscreen constituents

3. Excited state intramolecular proton transfer (ESIPT): from principal photophysics to the development of new chromophores and applications in fluorescent molecular probes and luminescent materials

4. Ab Initio Study of Potential Ultrafast Internal Conversion Routes in Oxybenzone, Caffeic Acid, and Ferulic Acid: Implications for Sunscreens

5. Probing the Ultrafast Energy Dissipation Mechanism of the Sunscreen Oxybenzone after UVA Irradiation

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