Half-sandwich rare-earth metal tris(alkyl) ate complexes catalyzed phosphaguanylation reaction of phosphines with carbodiimides: an efficient synthesis of phosphaguanidines
Author:
Affiliation:
1. Beijing National Laboratory for Molecular Sciences
2. MOE Key Laboratory of Bioorganic Chemistry and Molecular Engineering
3. College of Chemistry
4. Peking University
5. Beijing 100871
Abstract
Half-sandwich Y/Li ate complex displays better catalytic activity for phosphaguanylation reaction of phosphines with carbodiimides than the neutral yttrium complexes.
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2015/NJ/C5NJ01136A
Reference56 articles.
1. Mechanistic Considerations of the Catalytic Guanylation Reaction of Amines with Carbodiimides for Guanidine Synthesis
2. Recent development of synthetic preparation methods for guanidines via transition metal catalysis
3. Guanidines: from classical approaches to efficient catalytic syntheses
4. Titanacarborane mediated C–N bond forming/breaking reactions
5. Catalytic addition of alkyne C–H, amine N–H, and phosphine P–H bonds to carbodiimides: an efficient route to propiolamidines, guanidines, and phosphaguanidines
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