Dehydrogenation of hydrocarbons with metal-carbon multiple bonds and trapping of a titanium(ii) intermediate-Reference-Cited by-同舟云学术

Dehydrogenation of hydrocarbons with metal-carbon multiple bonds and trapping of a titanium(ii) intermediate

Published:2014 Issue:26 Volume:43 Page:9834-9837
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Hickey Anne K.¹²³,Crestani Marco G.¹²³,Fout Alison R.¹²³,Gao Xinfeng¹²³,Chen Chun-Hsing¹²³,Mindiola Daniel J.¹²³

Affiliation:

1. Department of Chemistry and Molecular Structure Center

2. Indiana University

3. Bloomington, USA

Abstract

Reacting (PNP)TiCH^tBu(CH₂^tBu) with 2,2′-bipyridine (bipy) in cyclohexane or heptane results in dehydrogenation of the solvent, cleanly producing cyclohexene and 1-heptene, respectively, and a Ti^II intermediate that is trapped by bipy.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT01037J

Reference20 articles.

1. Electronic Structure of 2,2′-Bipyridine Organotransition-Metal Complexes. Establishing the Ligand Oxidation Level by Density Functional Theoretical Calculations

2. Experimental and Computational Study of the Structural and Electronic Properties of FeII(2,2′-bipyridine)(mes)2 and [FeII(2,2′-bipyridine)(mes)2]−, a Complex Containing a 2,2′-Bipyridyl Radical Anion

3. Bis(2,2'-bipyridyl)diisopropoxymolybdenum(II). Structural and spectroscopic evidence for molybdenum-to-bipyridyl .pi.* bonding

4. Coordination of 2,2‘-Bipyridyl and 1,10-Phenanthroline to Substituted Ytterbocenes: An Experimental Investigation of Spin Coupling in Lanthanide Complexes

5. Unusual Reductive Coupling of Alkynes and Ketones: Reactivity of Titanacycles Supported by Dimethylsilylcalix[4]arene (DMSC) Ligands

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