Retrosynthetic approach to the design of molybdenum–magnesium oxoalkoxides
Author:
Affiliation:
1. Institute of Problems of Chemical Physics of the Russian Academy of Sciences
2. Chernogolovka, Russian Federation
3. A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
4. Moscow, Russian Federation
Abstract
A facile synthetic strategy based on a retrosynthetic philosophy was developed and employed for the preparation of the polynuclear Mo–Mg oxomethoxides – high valence precursors of N2 fixing catalysts.
Funder
Russian Foundation for Basic Research
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT01035C
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4. Carbon-Nitrogen Bond Formation by the Reaction of 1,2-Cumulenes with a Ditantalum Complex Containing Side-On- and End-On-Bound Dinitrogen
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3. Tri-, tetra-, and hexanuclear mixed-valence molybdenum clusters: structural diversity and catalysis of acetylene hydrogenation;Dalton Transactions;2016
4. Developing Pathways to the Synthesis of Low‐Valence Molybdenum Methoxides: Preparation, Characterization, and Redox Chemistry of Dimeric and Tetrameric Molybdenum Alkoxide Clusters;European Journal of Inorganic Chemistry;2015-01-08
5. Base promoted successive dealkylation steps of molybdenum alkoxides leading to a row of novel 1D and 2D polymeric frameworks of potassium–molybdenum oxomethoxides;Polyhedron;2015-01
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