The crystal structure and magnetic properties of a Zintl phase EuIrIn4: the first member of the Eu–Ir

The crystal structure and magnetic properties of a Zintl phase EuIrIn4: the first member of the Eu–Ir–In family

Published:2014 Issue:42 Volume:43 Page:15879-15886
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Sarkar Sumanta¹²³,Gutmann Matthias J.⁴⁵⁶,Peter Sebastian C.¹²³

Affiliation:

1. New Chemistry Unit

2. Jawaharlal Nehru Centre for Advanced Scientific Research

3. Bangalore, India

4. ISIS Facility

5. STFC-Rutherford Appleton Laboratory

6. Didcot, UK

Abstract

EuIrIn₄is the first member of the Eu–Ir–In family to be synthesized by the metal flux method using indium as the active flux. It is the first YNiAl₄type variant of RETX₄with 9th group transition metals and lanthanides.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT01620C

Reference58 articles.

1. KNa3In9: A Zintl Network Phase Built of Layered Indium Icosahedra and Zigzag Chains. Synthesis, Structure, Bonding, and Properties

2. Synthesis and Structure of Ca18Li5In25.07: A Novel Intergrowth of Li-Centered In12 Icosahedral Clusters and Electron-Precise Zintl Layers

3. Novel Arachno-type X56– Zintl Anions in Sr3Sn5, Ba3Sn5, and Ba3Pb5 and Charge Influence on Zintl Clusters

4. Zintl Phases in Alkali-Metal-Tin Systems: K8Sn25 with Condensed Pentagonal Dodecahedra of Tin. Two A8Sn44 Phases with a Defect Clathrate Structure

5. Zintl Phases: Transitions between Metallic and Ionic Bonding

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