Pd12MnL24 (for n = 6, 8, 12) nanospheres by post-assembly modification of Pd12L24 spheres-Reference-Cited by-同舟云学术

Pd₁₂M_nL₂₄ (for n = 6, 8, 12) nanospheres by post-assembly modification of Pd₁₂L₂₄ spheres

Published:2023 Issue:42 Volume:14 Page:11840-11849
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Bobylev Eduard. O.¹^ORCID,Passerini Leonardo²,de Zwart Felix J.¹^ORCID,Poole David A.¹^ORCID,Mathew Simon¹^ORCID,Huber Martina²^ORCID,de Bruin Bas¹^ORCID,Reek Joost N. H.¹^ORCID

Affiliation:

1. van't Hoff Institute for Molecular Sciences, University of Amsterdam, Science Park 904, 1098 XH Amsterdam, The Netherlands

2. Department of Physics, Huygens-Kamerlingh Onnes Laboratory, Leiden University, Niels Bohrweg 2, 2333 CA Leiden, The Netherlands

Abstract

Selective post-assembly modification of Pd12L24 nanospheres leads to nanospheres with exactly 6, 8 or 12 transition metal complexes at precise positions. The strategy leads to materials with unique composition and geometrical features.

Funder

Universiteit van Amsterdam

Nederlandse Organisatie voor Wetenschappelijk Onderzoek

Ministerie van Onderwijs, Cultuur en Wetenschap

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC03745B

Reference46 articles.

1. Dynamic Self-Assembly of an M3L6 Molecular Triangle and an M4L8 Tetrahedron from Naked PdII Ions and Bis(3-pyridyl)-Substituted Arenes

2. Self-Assembly of Pt(II) Spherical Complexes via Temporary Labilization of the Metal–Ligand Association in 2,2,2-Trifluoroethanol

3. Self-Assembly of M 30 L 60 Icosidodecahedron

4. Remarkable Stabilization of M12L24 Spherical Frameworks through the Cooperation of 48 Pd(II)−Pyridine Interactions

5. Self-Assembled M 24 L 48 Polyhedra and Their Sharp Structural Switch upon Subtle Ligand Variation