Thermoswitchable catalysis to inhibit and promote plastic flow in vitrimers-Reference-Cited by-同舟云学术

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Thermoswitchable catalysis to inhibit and promote plastic flow in vitrimers

Published:2024 Issue:19 Volume:15 Page:7061-7071
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Van Lijsebetten Filip¹,Maes Stephan¹^ORCID,Winne Johan M.¹^ORCID,Du Prez Filip E.¹^ORCID

Affiliation:

1. Polymer Chemistry Research Group, Centre of Macromolecular Chemistry (CMaC) and Laboratory of Organic Synthesis, Departement of Organic and Macromolecular Chemistry, Faculty of Sciences, Ghent University, Krijgslaan 281-S4, Ghent, 9000, Belgium

Abstract

We show that weaker acid catalysis has profound effects on the dynamicity of vinylogous urethane based polymer networks. Moreover, the dynamicity could be adjusted by changing electronic and steric parameters in the catalytic environment.

Funder

H2020 European Research Council

Bijzonder Onderzoeksfonds UGent

Fonds Wetenschappelijk Onderzoek

Universiteit Gent

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC00417E

Reference73 articles.

1. Utility of acid-base behavior of excited states of organic molecules

2. Enzyme reactivity from an organic perspective

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4. Some Relations between Reaction Rates and Equilibrium Constants.

5. Carboxylic acid-amine equilibria in nonaqueous solvents

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