Neutral, closed-shell nickel bis(2-alkylthio-thiazole-4,5-dithiolate) complexes as single component molecular conductors
Author:
Affiliation:
1. Univ Rennes
2. CNRS
3. ISCR (Institut des Sciences Chimiques de Rennes) – UMR 6226
4. F-35000 Rennes
5. France
6. Laboratoire de Physique des Solides UMR 8502 CNRS-Université de Paris-Sud
7. 91405 Orsay cedex
Abstract
Despite their closed-shell character, neutral bis(thiazole-4,5-dithiolate) nickel dithiolene complexes [Ni(RS-tzdt)2]0 (R = Me, Et) behave as single component conductors.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT00818C
Reference41 articles.
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2. Conducting Metal Dithiolene Complexes: Structural and Electronic Properties
3. Dithiolene Chemistry , in Prog. Inorg. Chem , ed. E. I. Stiefel , 2004 , vol. 52
4. Concerning the band structure of D(M(dmit)2)2 (D=TTF,Cs,NMe4); M=Ni,Pd) molecular conductors and superconductors: Role of the M(dmit)2 Homo and Lumo
5. Charge density wave and metallic state coexistence in the multiband conductorTTF[Ni(dmit)2]2
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1. Synthesis, electrical conductivity and NIR absorption of some metal dithiolene complexes: some recent developments;Indian Journal of Chemistry;2023-03-17
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3. Comparative Structural Studies of Ni vs . Au Metal Bis‐dithiolene Complexes with a Thiazole Backbone [M(R‐thiazdt) 2 ];European Journal of Inorganic Chemistry;2022-08-05
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5. Hydrogen bonding interactions in single component molecular conductors based on metal (Ni, Au) bis(dithiolene) complexes;Dalton Transactions;2020
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