Aromatic stabilization of functionalized corannulene cations
Author:
Affiliation:
1. Department of Chemistry
2. Illinois Institute of Technology
3. Chicago
4. USA
Abstract
Conservation of aromaticity of 6-membered rings along with vanishing anti-aromatic character of central 5-membered ring was found to be the main reason for exceptional stability ofhub-isomer. Functionalization of corannulene moiety atrim- orspoke-site resulted in dramatic elimination of aromaticity of 6-membered rings thus resulting to dramatic reduce of their stability.
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2016/CP/C5CP07002C
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