An unprecedented nanocage-like and heterometallic [MoIV3O4]-polyoxomolybdate hybrid
Author:
Affiliation:
1. State Key Laboratory of Structural Chemistry
2. Fujian Institute of Research on the Structure of Matter
3. Chinese Academy of Sciences
4. Fuzhou
5. P. R. China
Abstract
A general synthetic route toward [MoIV3O4]-POMs is established to yield the first Mo4+–Mo5+–Mo6+ nanocage cluster, Na[(MoIV3O4)4MoV4MoVI3O27(OH)Py12] (1) and the first heterometallic hybrid, H2[(MoIV3O4)MoVI10Zn(PO4)4(OH)2O27py3] (2) (Mo4+, pink; Mo5+, green; Mo6+, black green; P, yellow; Zn, aqua.
Funder
National Natural Science Foundation of China
Chinese Academy of Sciences
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/DT/C7DT04309K
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