Strong non-Arrhenius behavior at low temperatures in the OH + HCl → H<sub>2</sub>O + Cl reaction due to resonance induced quantum tunneling-Reference-Cited by-同舟云学术

Strong non-Arrhenius behavior at low temperatures in the OH + HCl → H₂O + Cl reaction due to resonance induced quantum tunneling

Published:2022 Issue:26 Volume:13 Page:7955-7961
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Xu Xin¹^ORCID,Chen Jun²^ORCID,Lu Xiaoxiao¹^ORCID,Fang Wei¹^ORCID,Liu Shu¹^ORCID,Zhang Dong H.¹^ORCID

Affiliation:

1. State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China

2. State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, Fujian, China

Abstract

The OH + HCl reaction possesses many Feshbach resonances trapped in the hydrogen bond well in the entrance channel, which substantially enhance the reaction rates at low temperatures.

Funder

National Natural Science Foundation of China

Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC01958B

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