Highly diastereoselective C → N acyl rearrangement in polysubstituted pyrrolidine 2,2-dicarboxylates. Stereocontrolled synthesis of densely functionalized prolines-Reference-Cited by-同舟云学术

Highly diastereoselective C → N acyl rearrangement in polysubstituted pyrrolidine 2,2-dicarboxylates. Stereocontrolled synthesis of densely functionalized prolines

Published:2018 Issue:6 Volume:5 Page:933-942
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Reboredo Silvia¹²³⁴,García-Marijuan Ainara¹²³⁴,Uria Uxue¹²³⁴,Reyes Efraím¹²³⁴,Carrillo Luisa¹²³⁴^ORCID,Ugarriza Iratxe¹²³⁴,Vicario Jose L.¹²³⁴^ORCID

Affiliation:

1. Department of Organic Chemistry II

2. University of the Basque Country (UPV/EHU)

3. 48080 Bilbao

4. Spain

Abstract

A fully diastereoselective C–N acyl transfer reaction operates in enantiopure densely substituted pyrrolidine 2,2-dicarboxylates.

Funder

Eusko Jaurlaritza

European Cooperation in Science and Technology

Euskal Herriko Unibertsitatea

Ministerio de Economía y Competitividad

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/QO/C7QO00793K

Reference59 articles.

1. Recent advances in the enantioselective 1,3-dipolar cycloaddition of azomethine ylides and dipolarophiles

2. Catalytic Enantioselective 1,3-Dipolar Cycloadditions of Azomethine Ylides for Biology-Oriented Synthesis

3. Recent advances in the catalytic asymmetric 1,3-dipolar cycloaddition of azomethine ylides

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